High-temperature electrolysis (HTEL) offers the highest efficiency of all known water electrolysis technologies. However, compared to low-temperature electrolysis technologies, it is still at a lower level of technological maturity. Conventional cell concepts rely on ceramic support structures, which provide numerous advantages but also present drawbacks, particularly regarding their thermo-mechanical properties. Alternatively, cell concepts based on metallic support structures exhibit excellent mechanical strength but require fundamentally different manufacturing processes. The most common support structures are perforated metal sheets or porous sintered metals. In both cases, corrosion of the support material is a key factor limiting the cell lifetime.
Within the framework of the BMFTR-funded collaborative research project SOCool, a completely novel approach to the fabrication of metal-supported solid oxide electrolysis cells (MS-SOECs) will be developed. The proposed cell concept is based on separating the mechanical function of the substrate from the transport of electronic charge carriers, thereby overcoming corrosion as the primary degradation mechanism. To realize this concept, feasibility studies on coating the innovative support structure must be carried out. The central challenge is the deposition of oxide-ceramic functional layers onto metallic components with complex microstructures. The objective is to create a multilayer coating with a graded particle size distribution, thereby establishing the prerequisites for the subsequent deposition of a dense electrolyte layer.
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